Design Process of CSTR for Production Carboxyl Methyl Cellulose

Abstract

The aim of this study is to generate tools for utilizing Cellulose Biomasses Polymers from Palm Frond Fabricating Unit Design, Principles of material balance and volume equations were perform on the Reactor system to derive model equations applied in obtaining the reactor design parameters. Synthesize and characterize of carboxyl methyl cellulose (CMC) from Phoenix dactyliferaL, Date palm (leaves by etherification reaction using sodium mono chloroacetic acid (MCA)) and sodium hydroxide. Crystallinity of purified cellulose and (CMC) with degree of substitution of 0.77 and a percentage of produced CMC was 71%. The hydrolysis and dehydration reaction of Cellulose and Sodium hydroxide and Sodium monochord acetic acid respectively to Caboxylmethylcellulose is Exothermic. A cooling jacket incorporated to account for the supply and treatment of heat liberated. As a result, an integrated design of the CSTR reactor was presented to produce 150 tons/year of CMC with a volume of 2435.26 dcm3.

Country : Sudan

1 Wafaa M. Osman2 Ahmed A. Ibrahim3 Abdullah B. Karma4 Amel A.A. Nimir

  1. Downstream General Directorate, Refining and Petrochemical Department, Ministry of Energy and Petroleum, Khartoum, Sudan
  2. Petroleum Engineering Department, Sudan University of Science and Technology, Khartoum, Sudan
  3. Chemical Engineering Department, Karary University, Khartoum, Sudan
  4. Refining and Transportation Department, Sudan University of Science and Technology, Khartoum, Sudan

IRJIET, Volume 7, Issue 2, February 2023 pp. 27-35

doi.org/10.47001/IRJIET/2023.702004

References

  1. Dorel Feldman, “Polymer History, Designed Monomers and Polymers,”11:1, pp.1-15, DOI: 10.1163/156855508X292383, (2008).
  2. Granström, M., “Cellulose derivatives: synthesis, properties and applications,” PhD thesis, University of Helsinki, Finland, (2009).
  3. Bono, A.,P. H. Ying, F. Y. Yan, C. L. Muei, R. Sarbatly, and D. Krishnaiah, “Synthesis and characterization of carboxymethyl cellulose from palm kernel cake,” Advances in Natural and Applied Sciences, vol. no. 3(1), pp.5-12, 2009.
  4. Sun, X.F., Sun, R.C., Tomlinson, J. and Baird, M.S “Degradation of wheat straw lignin and hemicelluloses polymers by a totally chlorine-free method. Polymer Degradation and Stability,” vol. no. 83(1), pp.38-57, (2004).
  5. Latif, A., Anwar, T. and Noor, S. “Two-step synthesis and characterization of carboxymethylcellulose from rayon grade wood pulp36, and cotton linter,” Journal of the Chemical Society of Pakistan, vol. no. 29 (2), pp.143-150, (2007).
  6. Rahman, M. S., Hasan, M. S., Nitai, A. S., Nam, S., Karmakar, A. K., Ahsan, M. S., “Recent Developments of Carboxymethyl Cellulose. Polymers,” vol. no. 13(8), pp. 1345. doi: http://doi.org/ 10.3390/polym13081345, (2021).
  7. Adinugraha, M.P. and Marseno, D.W., “Synthesis and characterization of sodium carboxymethylcellulose from Cavendish banana pseudo stem (Musa cavendishi LAMBERT),” Carbohydrate Polymers Journal, vol. no. 62(2), pp.164-169, (2005).
  8. Mondal, M.I. H, Yeasmin, M.S. and Rahman, M.S., “Preparation of food grade carboxymethyl cellulose from corn huskagro waste,” International journal of biological macromolecules, pp.79, 144-150, doi:http://doi.org/10.1016/j.ijbiomac.2015.04.061, (2015).
  9. Benyounes, K., Mellak, A. and Benchabane, A., "The Effect of Carboxymethylcellulose and Xanthan on the Rheology of Bentonite Suspensions," Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, vol. no. 32, pp.1634-1643, 09/2010 and 07/2015.
  10. Dapia,S., Tovar, C. A., Santos, V. and Parajo, J. C. “Rheological behavior of  carboxymethylcellulose manufactured from TCF-bleached Milox pulps,” Food Hydrocolloids, vol. no. 19, pp.313–320, (2005).
  11. ELrayah, A.Ahmed, Mohamed,A.Amani,M. I. IBRAHIM and K. H.AHMED, “Drilling Fluids Additive Sodium Carboxylmethyl Cellulose (CMC)Produced from Palm Frond,” IPPTC Organization Committee, International Petroleum and Petrochemical Technology Conference, Shanghai, China,(26-28 August 2020).
  12. Kukrety, A., Singh, R.K., Singh, P. and Ray, S.S., “Comprehension on the synthesis of carboxymethylcellulose (CMC) utilizing various cellulose rich waste biomass resources,” Waste and biomass valorization, vol. no. 9(9), pp.1587-1595, (2018).
  13. Kutsenko, L.I., Bochek, A.M., Vlasova, E.N. and Volchek, B.Z., “Synthesis of carboxymethyl cellulose based on short fibers and lignified part of flax pedicels (boon),” Russian journal of applied chemistry, vol. no. 78(12), pp.2014-2018, (2005).
  14. Octave L., “Chemical reactions engineering,” 3rd edition, Wileybook, New Delhi, pp. 84-127, (2001).
  15. Yuldoshov,Sh.A., “Kinetics of solid-phase carboxymethylation of cotton and microcrystalline cellulose,” Macro molecules India Journal, vol. no. 10, pp. 69-72, (2014).
  16. Coulson, J. M., Richardson, J. F., Bachhurst, J. R. and Harker, J. H., “Biochemical Reactors & Process Control,” vol. no. 3, 3ed edition Chemical Engineering Book, pp. 42-44, (2005).
  17. Ray Sinnott and Gavin Towler, “Chemical Engineering Design Commonly used materials of construction,” vol.no. 6, 4th Edition Chemical Engineering Book, pp. 295-300, (2005).